The solar-driven photocatalytic splitting of water into hydrogen and oxygen is a potential source of clean and renewable fuels. However, four decades of global research have proven this multi-step reaction to be highly challenging. The design of effective artificial photo-catalytic systems will depend on our ability to correlate the photocatalyst structure, composition, and morphology with its activity.
I will present our strategies, and most recent results, in taking photocatalyst production to new and unexplored frontiers. I will focus on unique design of innovative nano scale particles, which harness nano phenomena for improved activity, and methodologies for the construction of sophisticated heterostructures. I will share our design rules and accumulated insights, which enabled us to obtain a perfect 100% photon-to-hydrogen production efficiency, under visible light illumination, for the photocatalytic water splitting reduction half reaction. Finally, I will describe our future designs of systems capable of overall water splitting and genuine solar-to-fuel energy conversion.