Semiclassical methods for solving the Time Dependent Schroedinger equation (TDSE) bridge the gap between quantum and classical mechanics. We have recently developed a semiclassical method based on complex valued classical trajectories. Here we combine the method with complex time and apply it to two different potentials: the Eckart potential and the centrifugal barrier potential. We analyse the ability of complex trajectories and complex time to describe classically allowed and classically forbidden processes on the same footing.1-5
1. Yair Goldfarb, Ilan Degani, and David J. Tannor. Bohmian mechanics with complex action: A new trajectory-based formulation of quantum mechanics. J. Chem. Phys., 125(23):231103, December 2006.
2. Kenneth G. Kay. Time-dependent semiclassical tunneling through barriers. Physical Review A, 88(1), July 2013.
3. Noa Zamstein and David J. Tannor. Communication: Overcoming the root search problem in complex quantum trajectory calculations. J. Chem. Phys., 140(4):041105, January 2014.
4. Jakob Petersen and Kenneth G. Kay. Wave packet propagation across barriers by semiclassical initial value methods. J. Chem. Phys., 143(1):014107, July 2015.
5. Werner Koch and David J. Tannor. Wavepacket revivals via complex trajectory propagation. Chemical Physics Letters, 683:306–314, September 2017.