Mechanically Robust Slippery Liquid-Infused Porous Surfaces Based on Electrodeposited Porous Tungsten Bronze Films 

Alexander Tesler 1,2 Philseok Kim 2 Joanna Aizenberg 1,2,3
1School of Engineering and Applied Sciences, Harvard University, Cambridge, Massachusetts, USA
2School of Engineering and Applied Sciences, Wyss Institute for Biologically Inspired Engineering, Cambridge, Massachusetts, USA
3School of Engineering and Applied Sciences, Kavli Institute for Bionano Science and Technology, Cambridge, Massachusetts, USA

A simple, nontoxic and inexpensive method to prepare mechanically robust surfaces that repels a variety of liquids and solids has immediate relevance in many industrial applications. Unwanted interactions between liquids and surfaces are currently a limiting factor nearly everywhere liquids are handled or encountered. Most state-of-the-art liquid repellent surfaces are modeled after lotus leaves, which are known to exhibit superhydrophobicity and self-cleaning. Despite over a decade of research, these surfaces are still plagued with problems that restrict their practical applications.

Recently, the slippery liquid-infused porous surfaces (SLIPS) technology was introduced by our group. SLIPS technology is inspired by the Nepenthes pitcher plant and provides unique capabilities that are unmatched by any other liquid-repellent surface technologies. SLIPS surfaces function under high pressure conditions, instantly self-heal imperfections, provide optical transparency, repel ice nucleation, and are ultra-repellent to pure and complex fluids such as blood, crude oil, and brine. They also repel solids such as ice and wax. These properties allow the slippery surfaces to be used in a wide variety of applications and environments. Moreover, the slippery surfaces can be constructed from a broad range of simple, inexpensive materials without the need for specialized fabrication facilities.

Here we used a stainless steel, which is widely used in biomedical, household and industrial equipment, surgical instruments, kitchen appliances, transport and architecture, as a substrate. Inexpensive and environmentally friendly electrodeposition process used to form a thin layer of nanostructured tungsten bronze. Such films are mechanically robust and can be functionalized to increase its hydrophobicity, ideal for integration with SLIPS technology. Moreover, electrochemical deposition provides various control parameters for optimization of the film morphology. We will present that slippery stainless steel surfaces can be optimized to repel simple and complex fluids, reduces ice formation, accelerates frost removal and prevent adhesion of biofilms.

atesler@seas.harvard.edu








 




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